The People's Choice Awards at the Nokia Theatre in LA on Wednesday night was a star-studded affair with plenty of famous faces in the crowd and hanging out backstage. Jennifer Aniston popped up in a leather number to accept her favorite comedic movie actress award and met up with Ellen DeGeneres and Portia de Rossi behind the scenes. Naomi Watts shared a moment with Robert Downey Jr., while Ian Somerhalder congratulated Lea Michele on her comedic TV actress win. Matt Bomer posed for a cute snap with Chloë Moretz, and Sandra Bullock chatted with Regina King after Regina introduced her as the favorite humanitarian honoree. There were lots more exciting moments while the show was underway, so click through to see them all, and make sure to check out all the red-carpet action too!