Blake Lively stepped out for Gucci's Chime For Change event at Macy's in NYC on Tuesday. She bundled up in a superchic blue trench coat to promote the brand's latest campaign — Blake has been a spokeswoman for Gucci and supporter of its Chime For Change charity organization for the past two years — and she didn't seem to waste any time getting back to work after walking the red carpet at Monday night's Met Gala in Manhattan. Blake arrived in serious style with her husband, Ryan Reynolds, for the latest in only a handful of major public outings since they tied the knot in 2012. It may have been Ryan's first time at the Met Gala, but it looked like he had a great time; he and Blake stayed quite close throughout the evening and showed enough steamy PDA to land them in first place in our sexiest couple poll. Keep reading for more photos of Blake at Gucci's event in NYC.