Brad Pitt and Angelina Jolie in NYC

Power couple Angelina Jolie and Brad Pitt split up to take care of separate appointments this evening in the Big Apple. She exited a building in another wintry white jacket while across town Brad was spotted leaving Manhattan's Bloomberg building carrying a small red bag and some papers. The Jolie-Pitts arrived in NYC over the weekend prior to last night's premiere of her directing debut In the Land of Blood and Honey. She stepped behind the camera to pen and direct the tale of war, though for her next project it seems like she's ready to return to acting. She's already in negotiations to begin shooting Maleficent and an untitled Ridley Scott project next year and is now adding a third project into contention. Angelina is reportedly considering a role in Luc Besson's next thriller, which will likely have a futuristic spin.