Brad Pitt and Angelina Jolie National Portrait Gallery Pictures

Angelina Jolie and Brad Pitt visited London's National Portrait Gallery this afternoon. The couple checked out the Lucian Freud exhibit before heading out and into a waiting car. Brad and Angelina left the kids at home for this outing, but they did recently see a matinee showing of Billy Elliot the Musical with their family.

The whole crew will soon head south to France, where Brad and Angelina are expected at the Cannes Film Festival. Brad has Killing Them Softly premiering at the event and we're looking forward to a glamorous appearance from him and Angelina on the red carpet. They've attended in years past and its no surprise that their star status has landed them among the top spots in our PopSugar 100 faceoff game — there's still time to play for the chance to win $2,500 in cash!