Marilyn Monroe, Ali MacGraw, Nicole Kidman . . . and Brad Pitt? The handsome actor joins the ranks of some Hollywood's most gorgeous leading ladies as the new face of Chanel No. 5 in a campaign launched today by the French fragrance. Sporting long hair and a goatee, the actor transforms into a brooding philosopher of perfume in the 30-second "There You Are" spot. Brad muses abstractly on everything from the Earth's orbit to one special-smelling lady in his life — and even speaks directly into the camera for several heart-pounding moments. But are we giggling or blushing? Watch today's PopSugar Rush and make your call on Brad's intense scent ad.