Hollywood's finest stepped out for the People's Choice Awards at LA's Nokia Theater on Wednesday night. Stars like Nina Dobrev , Allison Williams, and Sandra Bullock  showed up in style for the event, which marked the official kickoff of the 2014 award season! The stars of 2 Broke Girls, Kat Dennings and Beth Behrs, were clad in gorgeous gowns before heading backstage to begin their hosting gig, while Heidi Klum  and Malin Akerman kept things sexy in low-cut numbers. Ian Somerhalder  brought his famous smolder to the show, while Anna Faris  and Chris Pratt looked adorable as they coupled up on the carpet. Keep on reading to see all the stars who brought their A-game to the People's Choice Awards!
Nina Dobrev looked super hot  at the People's Choice Awards.
Girls star Allison Williams  was a vision in her colorblock dress at the People's Choice Awards.
Sandra Bullock was the belle of the ball  as she arrived for the PCAs.
Jessica Alba made a glamorous return  to the PCAs red carpet.
Heidi Klum  sported her signature sexy look at the People's Choice Awards.
Lucy Hale sported a bright floral print for her turn on the red carpet.
Allison Janney looked amazing in black.
Arrow star Stephen Amell suited up in blue.
Bailee Madison attended the PCAs.
People's Choice Awards hosts Kat Dennings and Beth Behrs  showed up in style for their gig.
Malin Akerman showed off her assets on the red carpet.
Naya Rivera debuted a new, lighter hair shade on the People's Choice Awards red carpet.
Queen Latifah  wore a black dress and heels on the PCAs red carpet.
Sara Bareilles arrived for her night on stage.
The Walking Dead star Norman Reedus walked the red carpet.
Anna Faris  and Chris Pratt made an adorable couple on the PCAs red carpet.
Jennifer Hudson dropped jaws  on the red carpet in her sleek white dress.
Sarah Michelle Gellar  was a vision in black and white at the People's Choice Awards.
Emily Deschanel hit the red carpet for the People's Choice Awards.
Melissa Joan Hart attended the People's Choice Awards.
Ian Somerhalder brought his smolder , naturally, to the PCAs red carpet.
Shemar Moore looked dapper in a gray suit on the red carpet.