The biggest stars on TV will come together this afternoon for the Primetime Emmy Awards ! Before the big show, all eyes will be on the red carpet fashion and we're especially excited to see the hot couples. Jason Sudeikis already confirmed he's joining January Jones . Neil Patrick Harris  and David Burtka will attend together after already scoring two statues . Newlyweds Emily Blunt  and John Krasinski  are expected to be there, as are Anna Paquin  and Stephen Moyer  who just tied the knot a week ago . Humanitarian honoree George Clooney  is bringing Elisabetta Canalis, while Amy Poehler  and Will Arnett  are stepping out after welcoming their second baby . So tell us — which couple are you most excited to see tonight?