The biggest stars on TV will come together this afternoon for the Primetime Emmy Awards! Before the big show, all eyes will be on the red carpet fashion and we're especially excited to see the hot couples. Jason Sudeikis already confirmed he's joining January Jones. Neil Patrick Harris and David Burtka will attend together after already scoring two statues. Newlyweds Emily Blunt and John Krasinski are expected to be there, as are Anna Paquin and Stephen Moyer who just tied the knot a week ago. Humanitarian honoree George Clooney is bringing Elisabetta Canalis, while Amy Poehler and Will Arnett are stepping out after welcoming their second baby. So tell us — which couple are you most excited to see tonight?