2009 was a big one for the Jolie-Pitts, though they didn't add to their big family this year! First up was awards season, which included Oscar nominations for both Brad and Angelina. His worldwide promotional tour for Benjamin Button included a stop in Japan, where Knox and Vivienne made their public debut. Soon, Brad kicked off red carpets for Inglourious Basterds and Angelina started to film Salt, but of course there was time for philanthropic projects in New Orleans, Iraq, and Syria, among others. Take a look back at some of the year's most memorable Jolie-Pitt moments and check out the rest of our Best of 2009 slideshows and polls here.