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Jessica Biel and Justin Timberlake at Met Ball 2012 (Video)

Video: See Justin and Jessica's Engagement Glow and All the Met Gala Couples!

Justin Timberlake and Jessica Biel made their first official postengagement appearance last night at the annual Costume Institute Gala in New York. See their sweet red-carpet exchange and check out more hot couples at the Met Gala such as Gisele Bundchen and Tom Brady in today's PopSugar Rush.

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Jessica Biel and Justin Timberlake make their first post-engagement appearance! Hey there, I'm Karli Bulnes. See the future Mr. and Mrs. Timberlake lead the way for a pack of happy couples at the Met Ball when PopSugar Rush continues right after this! The 2012 Costume Institute Gala is considered the biggest nights in the fashion world, but the evening also doubled as date night for many of our favorite famous pairs. PopSugar editor Britt Stephens is here with the scoop on all the couples who hit the red carpet. Hey Britt! Hi! Let's start with Justin Timberlake and Jessica Biel, who paid homage to the theme of the evening by wearing head to toe Prada. Right, Jessica went with Prada, while Justin wore Tom Ford. This is their first official outing since becoming engaged over the holidays. It's their third time together at the Met Ball, they also attended in 2009 and 2010. They were in the mood to celebrate since JT was heard saying they were going to go find the champagne. Well they certainly have a lot to celebrate! Next up, what did you think about Givenchy-wearing Gisele Bundchen and Tom Brady, also in a Tom Ford suit? Again, this couple is considered a regular at this event. They turned things up a notch this year by kissing on the red carpet and sporting matching slicked-back hairdos. Tom's was more of a fauxhawk, which is quite a departure from his longer look last year, but Gisele has said she loves Tom's hair any which way. The couples just seemed to keep on coming last night — Emily Blunt and John Krasinski, Julianne Hough and Ryan Seacrest, Kristen Bell and Dax Shepherd, Amy Poehler and Will Arnett, the list goes on and on, but who were you hoping to see that didn't actually turn up? Well, Nina Dobrev looked dynamite in Donna Karan and she met up with boyfriend Ian Somerhalder at the afterparty, which was at Top of the Standard, but it would have been awesome to see them together in their Donna Karan looks. Also, Beyoncé made another much talked about entrance. Last year, Jay-Z helped her up the steps, but this year she was solo. I would have loved to see the new parents together on this glamorous night. And finally, where was Miranda Kerr and Orlando Bloom? Right? I thought they would have been there, too. Well, thanks Britt! For all the red carpet, afterparty, and behind-the-scenes pics from the Met Ball, head to! I'm Karli Bulnes and thanks for watching PopSugar Rush!

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