Blake Lively moved from Gossip Girl star to big-screen leading lady this year. Her small but acclaimed part in The Town showed she's more than just a pretty face on the CW show, and this Summer, she stars opposite Ryan Reynolds in Green Lantern. Blake's status in the fashion world was further cemented when she was selected as the face of Chanel Mademoiselle handbags. As Karl Lagerfeld and Anna Wintour's darling, Blake is a staple at fashion weeks around the world and is known for her daring and sexy red-carpet choices. Blake split with longtime love Penn Badgley, and was linked to a number of high-profile men before stepping out with new boyfriend Leonardo DiCaprio at the Cannes Film Festival.