Reese Witherspoon had a year full of highlights both professional and personal since landing at number three in the 2010 PopSugar 100. After a year-long romance, Reese announced her engagement to Jim Toth over the holidays, and the two tied the knot on her Ojai estate in April. The good girl actress celebrated the release of two big movies — first up was How Do You Know with Paul Rudd and Owen Wilson, followed by Water For Elephants alongside Robert Pattinson. She may be the envy of Twilight fans everywhere for getting to kiss Robert, but she only has eyes for Jim and their family-filled weekends around LA. Reese also remained active in her role with Avon and was honored with the Generation Award at the MTV Movie Awards.