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Amy Poehler and Will Arnett

We thought this funny couple would last forever, but there was nothing to laugh about when they announced their split in September 2012. They were together for nine years and have two children.

Read More Will ArnettAmy PoehlerGwyneth PaltrowJessica SimpsonKatie HolmesJennifer LopezCelebrity BreakupsMaria Shriver