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Sienna Miller and Jude Law, Alfie

  • The onscreen love story: Playboy Alfie romances everyone, everywhere, every night, but he briefly tries to settle down with Nikki, until their relationship proves to be too stormy.
  • The offscreen love story: Law and Miller met on the Alfie set and became engaged soon after . . . until Law cheated on Miller with his kids' nanny. But then! They got back back together in 2009, but broke up again, and now Miller is with Tom Sturridge, and the two have a child together.

Image Source: Everett Collection