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Amy Poehler and Will Arnett

Arrested Development's George — aka "Gob" — marries a seal dealer who eventually joins the army to avoid her feelings for Gob's brother-in-law, Tobias. The quirky duo is played by then-married couple Will Arnett and Amy Poehler, who started dating in 2000, got married in 2003, and announced their separation in September 2012.

Image Sources: Fox and Getty