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Liz and Jack, 30 Rock

The best thing about these two is that they are so vastly different yet can't help but be drawn to each other. Liz Lemon (Tina Fey) and Jack Donaghy (played by Alec Baldwin) start out as antagonists but quickly form an unbreakable bond. They look out for each other — like when Jack accompanies a nervous Liz to her high school reunion and when Liz takes the attention off an embarrassed Jack by dancing on stage in her bra at a company retreat. By the end of the series, they are close friends and confidants, with Jack even telling her, "Lemon, I honestly don't know what I'd do without you."

Source: NBC
Read More Alec BaldwinTina Fey