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Captain Hook and Emma

In the show's sexiest pairing, the iconic pirate has fallen for the beautiful savior. Like her parents' relationship, this flirtation started out with these two as foes, but Emma softens toward Hook (I mean, look at him). Things have been heating up (the L word is finally said), but considering she's now the Dark One, they might be on a little break in season five.

Image Source: ABC
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