The celebrity designer train just got a huge dose of A-list — that's because Angelina Jolie is hopping on it! The actress, UN goodwill ambassador, and busy mom has teamed up with former CEO of Asprey, Robert Procop, who's been designing pieces for her for the past decade, to create a classic collection she will also likely wear. The first of the duo's collaboration came to life on the red carpet at Salt's Berlin premiere (below). You can also see some pieces — namely a vintage diamond choker and yellow sapphire, cushion-cut earrings — in Angelina's new flick, The Tourist. But unlike many celebrity lines, this collection won't be on sale in stores. Rather, it will be sold privately through Procop's clients, with all of the proceeds going to her charity, the Education Partnership for Children of Conflict.