It was a "congratulations, eh!" to Ryan Reynolds, who became the first Canadian sexiest man alive in 2010. That year he starred in Buried and had numerous award show nominations for his previous year's roles in The Proposal and X-Men Origins: Wolverine — more than one of which had to do with kissing his costar Sandra Bullock. Like many of the other past winners, Ryan was a part of an all-star couple at the time, having recently married Scarlett Johansson. Sadly, though, they broke things off by the end of that year.