No. 1 on the 2008 PopSugar 100 list is Angelina Jolie! This A-list devoted mom and humanitarian continues to impress us with her work around the world, on the big screen, and at home with her family. There's no question — no one is bigger than Angelina these days, which also helped score her the title of your top female star of 2007. Whether she's hard at work or showing us her real life mighty heart, we can't wait to see what she does next.