Hollywood's finest stepped out for the People's Choice Awards at LA's Nokia Theater on Wednesday night. Stars like Nina Dobrev, Allison Williams, and Sandra Bullock showed up in style for the event, which marked the official kickoff of the 2014 award season! The stars of 2 Broke Girls, Kat Dennings and Beth Behrs, were clad in gorgeous gowns before heading backstage to begin their hosting gig, while Heidi Klum and Malin Akerman kept things sexy in low-cut numbers. Ian Somerhalder brought his famous smolder to the show, while Anna Faris and Chris Pratt looked adorable as they coupled up on the carpet. Keep on reading to see all the stars who brought their A-game to the People's Choice Awards!