Faith Hill [1] was the belle of the ball at the UNICEF Audrey Hepburn Society Ball in Houston on Friday. The country singer, who turned 48 in September, made a stunning appearance in a gorgeous red gown while arriving at the big event, which honored former First Lady Barbara Bush for her philanthropic efforts [2], including the Barbara Bush Foundation For Family Literacy. Faith lit up the red carpet while posing for photos with Barbara and took the stage inside for a special performance.

Last month, Faith and her husband, Tim McGraw [3], celebrated their 19th wedding anniversary [4]. Shorty after, Tim sat down with E! News and shared insights on his relationship [5] with his wife and what life is like with daughters Gracie, Maggie, and Audrey. Take a look at Faith's ultraglam moment, and then relive Faith and Tim's epic love story through pictures [6].