The Emmys are this Sunday, and in honor of one of the best award shows of the year, we've rounded up something other than a list of possible winners. While many people think of the Oscars when they reminisce about Hollywood's best couples, the Emmys red carpet usually sees more action. From Brad Pitt [1] and Jennifer Aniston [2] to Sarah Michelle Gellar [3] and Jerry O'Connell [4], the Emmys are almost as nostalgic as the TV Land lineup. Keep reading to see the former couples who attended the show together, then check out all the Hollywood breakups this year [5].

JC Chasez and Eva Longoria, 2004

Brad Pitt and Jennifer Aniston, 1999

Julia Roberts and Benjamin Bratt, 1999

Bruce Willis and Demi Moore, 1997

Sofia Vergara and Nick Loeb, 2011

James Franco and Marla Sokoloff, 2002

Jerry O'Connell and Sarah Michelle Gellar, 1998

Kelsey and Camille Grammer, 2001

Heidi Klum and Seal, 2011

Scott Foley and Jennifer Garner, 2001

Ellen DeGeneres and Alexandra Hedison, 2002

Jimmy Fallon and Tara Subkoff, 2002

Nina Dobrev and Ian Somerhalder, 2011

Amy Poehler and Will Arnett, 2011

Heather Locklear and Richie Sambora, 2002

Rebecca Romijn and John Stamos, 2000

Simon Cowell and Terri Seymour, 2003

Courteney Cox and David Arquette, 2003

Miss Piggy and Kermit the Frog, 2004

Ellen DeGeneres and Anne Heche, 1997

Melanie Griffith and Antonio Banderas, 2000

Helen Hunt and Hank Azaria, 1998

David Duchovny and Téa Leoni, 1998

Halle Berry and Eric Benét, 2000