Chuck and Vanessa may not be the best of pals on Gossip Girl, but real life couple Ed Westwick and Jessica Szohr were looking awfully friendly off set in NYC yesterday — shop her look here. The pair couldn't hide their big smiles as they walked a puppy around the city hand-in-hand and stopped for a quick make out session. The whole cast posed together for a steamy photo spread in Rolling Stone, but in real life they're pairing off like the hormone-driven high schoolers they play on TV.

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