Alessandra Ambrosio took her turn working on the new catalog for Victoria's Secret yesterday in Malibu. She, along with fellow Angel Adriana Lima, tried on a variety of skimpy combinations to pose for photographer Russell James. Alessandra was a big fan of the neon pieces in particular— make sure to check out FabSugar's lingerie guide as we get closer to Valentine's Day on Monday. Alessandra was spotted earlier this week perfecting her supermodel body at the gym, and all her sweat has paid off with recent appearances in the new issue of Love magazine and a range of ads for Koton beachwear. She also headed home to Brazil for Sao Paulo Fashion Week, where she joined Gisele Bundchen on the runway for Colcci. The long hours continue today for Alessandra, as she tweeted an early photo on her way back to the set.