Anne Hathaway and Valentino Garavani
Anne Hathaway's longtime friendship with Valentino Garavani is well-known in the industry, and the legendary designer was reportedly Anne's first choice to help create the gown she would wear to wed Adam Shulman in September 2012. Valentino revealed earlier that month that he "did the dress" for Anne, and that she is like a daughter to him. Her romantic off-the-shoulder gown was made of ivory silk point d'esprit tulle, had a train embroidered with satin flowers, and was hand-painted a soft pink hue. She also sported a '20s-inspired headpiece made of lace ribbon with an oversize flower that was adorned with small crystal beads.