Demi Lovato [1] and Wilmer Valderrama [2] are one of the cutest, tightest couples in Hollywood, and while the pair might be ready to tie the knot soon [3], when they first met five years ago, Wilmer wasn't a big fan of Demi. In an interview with On Air With Ryan Seacrest, Wilmer talked about falling in love with the "Cool For the Summer" singer and confessed she was the one who went after him, saying, "I wanted nothing to do with her, stay away from me. But if you know Demi, she won this one. She checked mate." But Wilmer also admitted it didn't take much time for him to give in and said he "fell in love with the person she really is," even though she was going through a difficult time in her life. [4] Watch the full interview above where Wilmer also talks about clubbing with Ryan Seacrest back in his single days and whether he knew That '70s Show costars Mila Kunis [5] and Ashton Kutcher [6] would end up together. Then, check out Demi and Wilmer's cutest moments [7].