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The former supermodel dated DiCaprio on and off between 2000 and 2005, People reported. While their split was reportedly amicable, according to Vanity Fair, Bündchen was the one who called it quits. "We know what we had. We were very young, and we grew together in a lot of ways," she told the publication in 2009. "We were just not meant to be boyfriend and girlfriend, but I respect him enormously, and I wish him nothing but the best." To this day, Bündchen is the only girlfriend DiCaprio has brought as a date to the Oscars (pictured above).