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Long before his days as a Netflix heartthrob, Barnet dated E! producer Cassie Maynard for approximately two years. Maynard and Barnet made their Instagram debut in November 2014 when the "Never Have I Ever" actor snapped a picture of the two while ice skating. Then, In December 2015, Barnet took to Instagram to celebrate their one-year anniversary with a collage of pictures of the couple festively posing in front of Christmas trees.
Throughout their relationship, Maynard frequently posted about their outings as a couple, but sometime after January 2017, it appeared the couple broke up, as their last picture together was shared on Jan. 10.