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Barnes was previously linked to longtime pal Julianne Hough. While neither of them ever confirmed a romantic relationship, they first sparked romance rumors in 2020 when they were photographed together in Los Angeles amid Hough's divorce from ex-husband Brooks Laich. They continued to be spotted together on multiple occasions through Augugust 2022.
In 2023, it's unclear if they were ever an official couple or just friends. Both Hough and Barnes still follow each other on Instagram, proving that romance or not, they're still good pals.
Prior to his rumored relationship with Hough, Barnes was linked to Felicity Jones, Meganne Young, and Tamsin Egerton.