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For five years, Jennifer Aniston and Brad Pitt were Hollywood's golden couple, but they ended their union in 2005 amidst cheating allegations involving the actor's Mr. and Mrs. Smith costar, Angelina Jolie. While the couple insisted that there was no affair, they did admit to "falling in love" on the set. In a Today show interview that year, Angelina told Ann Curry, "To be intimate with a married man, when my own father cheated on my mother, is not something I could forgive. I could not look at myself in the morning if I did that. I wouldn't be attracted to a man who would cheat on his wife."
Brad and Angelina dated for eight years before tying the knot in a top secret ceremony in August 2014, surrounded by their six children. They played an onscreen couple for the second time in 2015's By the Sea, but announced their plans to divorce in September 2016.