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30 TV Couples Who Also Dated in Real Life
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Leighton Meester and Sebastian Stan

In "Gossip Girl," Carter Baizen romances both Blair and Serena, but he has more of a legitimate relationship with Serena. However, the real-life legitimate relationship was between Leighton Meester and Sebastian Stan, who dated for a couple of years while the show was still on. The pair eventually split in 2010.

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