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As you can see, the sourdough starter more than doubled in size on day three, with "hooch" on the bottom. (It also still smelled terrible.) Hooch is a clear-to-dark-colored liquid that can collect at the top or the bottom of your starter when it's hungry and needs a feeding. It's normal and not a sign it's gone bad or moldy.
Watch out for a pink or orange tint or streak, however, as this is actually a sign that your sourdough starter has gone bad and should be tossed.