Popsugar Celebrity Celebrity Couples Celebrity Couples From the Past 66 Celebrity Couples You Most Definitely Forgot About May 13, 2020 by Lauren Turner View On One Page Photo 66 of 66 ADVERTISEMENT () Start Slideshow Share This Link Copy ← Use Arrow Keys → 66 Angelina Jolie and Billy Bob Thornton Angelina and Billy Bob met in 1999 while filming Pushing Tin and were married in 2000. They divorced in 2002 with Angelina taking custody of their newly adopted son, Maddox. Previous Next Start Slideshow Celebrity Couples