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After getting engaged in 2012, Brad and Angelina tied the knot on Aug. 23, 2014. The ceremony took place in France, and all six of Brad and Angelina's children were there to help them celebrate, though the couple managed to keep their planned nuptials under wraps from the public. The duo met on the set of the film Mr. & Mrs. Smith in 2005 and announced their plans to divorce in September 2016.